Event Title

The Superhalogen Properties of Gold Oxide Nanoclusters

Co-investigators

Pratik Koirala

Faculty Mentor

Anil Kandalam

Location

Farrar Hall, Room 131

Session

Session 3

Start Date

20-4-2012 10:45 AM

End Date

20-4-2012 11:45 AM

Description

Nanoclusters possessing anomalously large electron affinity (EA) values (EA > 3.7 eV) are termed "superhalogens." Superhalogens play an important role in a wide variety of areas, such as oxidizing agents, nucleating centers of aerosols in the atmosphere, and bio-catalysis. The existence of several superhalogens were first predicted and later verified experimentally. In this work, we present results of our density functional theory-based calculations, along with supporting experimental results, of the superhalogen behavior of Au3Ox [x = 0 - 4] clusters. This is the first-time gold oxide clusters have been reported to show superhalogen characteristics.

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Apr 20th, 10:45 AM Apr 20th, 11:45 AM

The Superhalogen Properties of Gold Oxide Nanoclusters

Farrar Hall, Room 131

Nanoclusters possessing anomalously large electron affinity (EA) values (EA > 3.7 eV) are termed "superhalogens." Superhalogens play an important role in a wide variety of areas, such as oxidizing agents, nucleating centers of aerosols in the atmosphere, and bio-catalysis. The existence of several superhalogens were first predicted and later verified experimentally. In this work, we present results of our density functional theory-based calculations, along with supporting experimental results, of the superhalogen behavior of Au3Ox [x = 0 - 4] clusters. This is the first-time gold oxide clusters have been reported to show superhalogen characteristics.